Identification and assignment of the absolute configuration of biologically active methyl-branched ketones from limnephilid caddisflies
Author
Summary, in English
Glands of the 4th and 5th abdominal sternite of the caddis flies Potamophylax latipennis, Potamophylax cingulatus, and Glyphotaelius pellucidus contain (S)-4-methyl-3-heptanone (4a), (4S,6S)-4,6-dimethyl-3-octanone (4b), and (4S,6S)-4,6-dimethyl-3-nonanone (4c). As shown by gas chromatography coupled with electrophysiological recordings, these ketones elicit a strong response in the insects' antennae. The structural assignment of the compounds was achieved on the basis of mass spectra, enantioselective synthesis, and gas chromatography on a chiral stationary phase.
Department/s
Publishing year
2001
Language
English
Pages
3175-3179
Publication/Series
European Journal of Organic Chemistry
Volume
2001
Issue
16
Links
Document type
Journal article
Publisher
John Wiley & Sons Inc.
Topic
- Biological Sciences
- Zoology
Status
Published
Research group
- Pheromone Group
ISBN/ISSN/Other
- ISSN: 1434-193X