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Structure and Bonding of Ethylene Oxide on Si(100)

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Author

Summary, in English

The bonding configuration and electronic structure of ethylene oxide adsorbed on Si(100)-(2 x 1) is investigated with fully polarization resolved X-ray absorption spectroscopy as well as with core level and valence band photoemission spectroscopy. Ethylene oxide is found to adsorb via a ring-opening reaction, where the molecule forms a five-membered ring together with the silicon surface dimer atoms inserting between a carbon and the oxygen atom. In the resulting geometry, the molecule is tilted out of the surface plane.

Department/s

Publishing year

2009

Language

English

Pages

16077-16082

Publication/Series

Journal of Physical Chemistry C

Volume

113

Issue

36

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Physical Sciences
  • Natural Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1932-7447