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Resonant Inelastic Scattering Spectra of Free Molecules with Vibrational Resolution

Author

  • Franz Hennies
  • Annette Pietzsch
  • Martin Berglund
  • Alexander Foehlisch
  • Thorsten Schmitt
  • Vladimir Strocov
  • Hans O. Karlsson
  • Joakim Andersson
  • Jan-Erik Rubensson

Summary, in English

Inelastic x-ray scattering spectra excited at the 1s(-1) pi* resonance of gas phase O-2 have been recorded with an overall energy resolution that allows for well-resolved vibrational progressions. The nuclear wave packet dynamics in the intermediate state is reflected in vibrational excitations of the electronic ground state, and by fine-tuning the excitation energy the dissociation dynamics in the predissociative B' (3) Pi(g) final state is controlled.

Department/s

Publishing year

2010

Language

English

Publication/Series

Physical Review Letters

Volume

104

Issue

19

Document type

Journal article

Publisher

American Physical Society

Topic

  • Natural Sciences
  • Physical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1079-7114