The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

On the stability of the hydrogen chloride complexes with ethylene and acetylene. A high resolution gas phase and ab initio study

På svenska

Author

  • Birute Mikulskiene
  • Alytis Gruodis
  • Valdas Sablinskas
  • Bengt Nelander

Summary, in English

The temperature dependencies of the intensities of the HCl stretching bands of the hydrogen chloride complexes with acetylene and ethylene have been used to obtain estimates of the dissociation enthalpies of the two complexes. Quantum chemical calculations on the Hartree Fock and DFT/B3LYP levels of theory have been combined with experimental data to give estimates of the intensities of the HCl stretching vibration in the two complexes.

Department/s

Publishing year

2003

Language

English

Pages

733-741

Publication/Series

Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy

Volume

59

Issue

4

Document type

Journal article

Publisher

Elsevier

Topic

  • Atom and Molecular Physics and Optics

Keywords

  • Hydrogen halide complexes
  • Stabilities
  • Quantum chemical calculations
  • Ethylene
  • Acetylene

Status

Published

ISBN/ISSN/Other

  • ISSN: 1386-1425