Decay of core excitations in bulk h-BN studied with resonant Auger spectroscopy
Author
Summary, in English
Non-radiative decay of core excitations at the B 1s and N 1s absorption edges of bulk hexagonal boron nitride (h-BN) has been studied with resonant Auger spectroscopy. In order to reproduce the bulk properties of the sample while keeping it electrically conducting, we have grown reasonably thick (more than 20nm) polycrystalline films of h-BN on a Ni(111) surface by thermal cracking of borazine vapor. The probability of the participator Auger process in the non-radiative decay of the B 1s(-1) pi* and N 1s(-1) pi* excitations has been found to be very high (31%) and rather low (below 0.5%), respectively. The drastic difference between the participator Auger decay probabilities of these two excitations has been explained in terms of different localization of the electrons promoted into the lowest unoccupied pi* state on the cationic (B) and anionic (N) sites.
Department/s
Publishing year
2005
Language
English
Pages
59-64
Publication/Series
Journal of Electron Spectroscopy and Related Phenomena
Volume
148
Issue
1
Document type
Journal article
Publisher
Elsevier
Topic
- Physical Sciences
- Natural Sciences
Keywords
- resonant Auger
- photoelectron spectroscopy
- boron nitride
- NEXAFS
- spectroscopy
Status
Published
ISBN/ISSN/Other
- ISSN: 0368-2048