The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

Microporous La-Metal-Organic Framework (MOF) with Large Surface Area

På svenska

Author

  • Souvik Pal
  • Asamanjoy Bhunia
  • Partha Jana
  • Subarna Dey
  • Jens Moellmer
  • Christoph Janiak
  • Hari Pada Nayek

Summary, in English

A microporous La-metal-organic framework (MOF) has been synthesized by the reaction of La(NO3)(3)center dot 6H(2)O with a ligand 4,4',4''-s-triazine-1,3,5-triyltri-p-aminobenzoate (TATAB) featuring three carboxylate groups. Crystal structure analysis confirms the formation of 3D MOF with hexagonal micropores, a Brunauer-Emmett-Teller (BET) surface area of 1074 m(2)g(-1) and high thermal and chemical stability. The CO2 adsorption capacities are 76.8 cm(3)g(-1) at 273 K and 34.6 cm(3)g(-1) at 293 K, a highest measured CO2 uptake for a Ln-MOFs.

Publishing year

2015

Language

English

Pages

2789-2792

Publication/Series

Chemistry: A European Journal

Volume

21

Issue

7

Document type

Journal article

Publisher

Wiley-Blackwell

Topic

  • Chemical Sciences

Keywords

  • adsorption
  • chemical stability
  • lanthanides
  • metal-organic frameworks
  • structure elucidation

Status

Published

ISBN/ISSN/Other

  • ISSN: 1521-3765