Substrate-selective catalysis.
Author
Summary, in English
Substrate selectivity is an important output function for the validation of different enzyme models, catalytic cavity compounds, and reaction mechanisms as demonstrated in this review. In contrast to stereo-, regio-, and chemoselective catalysis, the field of substrate-selective catalysis is under-researched and has to date generated only a few, but important, industrial applications. This review points out the broad spectrum of different reaction types that have been investigated in substrate-selective catalysis. The present review is the first one covering substrate-selective catalysis and deals with reactions in which the substrates involved have the same reacting functionality and the catalysts is used in catalytic or in stoichiometric amounts. The review covers real substrate-selective catalysis, thus only including cases in which substrate-selective catalysis has been observed in competition between substrates.
Department/s
Publishing year
2014
Language
English
Pages
13432-13481
Publication/Series
Chemistry: A European Journal
Volume
20
Issue
42
Document type
Journal article review
Publisher
Wiley-Blackwell
Topic
- Chemical Sciences
Status
Published
ISBN/ISSN/Other
- ISSN: 1521-3765