Systematic errors in isothermal micro- and nanocalorimetry
Author
Summary, in English
Results of calorimetric measurements are easily impaired by different kinds of systematic errors. Isothermal micro- and nanocalorimeters are particularly sensitive to such errors, as the measured thermal powers are very low. In this paper the occurrence and effects of such errors are discussed: calibration errors, baseline errors, problems with evaporation/condensation, sorption, pV-work, gaseous reactants and different kinds of mechanical effects. Several numerical examples are given.
Department/s
Publishing year
2005
Language
English
Pages
553-558
Publication/Series
Journal of Thermal Analysis and Calorimetry
Volume
82
Issue
3
Links
Document type
Journal article
Publisher
Akademiai Kiado
Topic
- Physical Chemistry
- Materials Engineering
Status
Published
ISBN/ISSN/Other
- ISSN: 1588-2926