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Metal controlled regioselectivity in the cyclometallation of 2-(1-naphthyl)-pyridine.

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Author

  • Mikhail Kondrashov
  • Sudarkodi Raman
  • Ola Wendt

Summary, in English

Cyclometallation of 2-(1-naphthyl)-pyridine is described. While cyclopalladation results in a five-membered metallacycle, cycloauration displays a completely orthogonal regioselectivity, resulting in the six-membered ring analogue. Bromination of the gold metallacycle results in the new C-H functionalisation product 2-(8-bromonaphth-1-yl)pyridine.

Publishing year

2015

Language

English

Pages

911-913

Publication/Series

Chemical Communications

Volume

51

Issue

5

Document type

Journal article

Publisher

Royal Society of Chemistry

Topic

  • Chemical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1364-548X