Ion Conductive Electrolyte Membranes Based on Co-Continuous Polymer Blends

Summary, in English

Solid electrolyte membranes based on comb-shaped poly(ethylene glycol) (PEG) doped with lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt in blends with poly(vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) have been studied. Membranes containing between 70 and 100 wt% PEG were prepared by a convenient two-step process where films containing a mixture of mono- and dimethacrylate-terminated PEG macromonomers, PVDF-HFP, LiTFSI, and a photoactivator were cast from acetone solutions, followed by UV-initiated polymerization of the macromonomers. Microscopy of the membranes revealed a phase separated morphology with a microporous PVDF-HFP network embedded in comb-shaped PEG. The membranes were thermally stable at temperatures below the melting point of PVDF-HFP at 140 °C. Dynamic mechanical analysis (DMA) in the tension mode showed that the mechanical properties of the membranes were greatly improved both by the addition of PVDF-HFP and of dimethacrylate-terminated PEG macromonomer. For example, the storage modulus at 25 °C and 1 Hz showed a three-fold increase after increasing the percentage of dimethacrylate-terminated PEG from 0 to 10 wt% in the macromonomer mixture. A broad shoulder on tan as a function of temperature indicated the existence of a PVDF-HFP rich amorphous interphase. At room temperature, the membranes containing more than 80 wt% PEG reached ionic conductivities exceeding 10–5 S cm–1.

• Author: Anette Munch Elmér; Bengt Wesslén; P Sommer-Larsen; K West; Helen Hassander; Patric Jannasch
• Department/s: Centre for Analysis and Synthesis
• Publishing year: 2003
• Language: English
• Pages: 2168-2176
• Publication/Series: Journal of Materials Chemistry
• Volume: 13
• Issue: 9
• Links: http://dx.doi.org/10.1039/b304462a
• Document type: Journal article
• Publisher: Royal Society of Chemistry
• Topic: Chemical Sciences
• Status: Published
• ISBN/ISSN/Other: ISSN: 1364-5501