Surface and bulk core level binding energy shifts in PtAu alloys
Author
Summary, in English
The surface core level shift of the 4f 7 2 level in a Pt2%Au and a Pt15%Au alloy has been investigated using high resolution synchrotron radiation excited photoelectron spectroscopy. The bulk and surface components in the recorded spectra have been extracted using a curve fitting procedure. The chemical shifts and the bulk-to-surface intensity ratios are consistent with a strong enrichments of Au to the alloy surfaces. The chemical shifts on nonsegregated surfaces have been measured on these alloys and on a Pt90%Au alloy using conventional XPS.
Publishing year
1985-09-02
Language
English
Pages
561-570
Publication/Series
Surface Science
Volume
160
Issue
2
Document type
Journal article
Publisher
Elsevier
Status
Published
ISBN/ISSN/Other
- ISSN: 0039-6028