The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

Multi-component self-assembly of molecule based materials by coordination networks and weak intermolecular synthons

På svenska

Author

  • Mohamed Ghazzali
  • Vratislav Langer
  • Krister Larsson
  • Lars Ohrstrom

Summary, in English

The coordination polymer [Fe(SCN)(2)(1,2-bis(4-pyridylmethylene)hydrazine)(2)](n) [Fe(phenanthroline)(3)](2n)(ClO4)(2n)center dot n1,2-bis(4-pyridylmethylene)hydrazine center dot 4nH(2)O 1 was crystallised from a MeOH/MeCN solution and the structure consists of layered (4,4) 2D-nets with supramolecular ([Fe(phen)(3)](2)bphz)(4+) units in the pores and disordered water and perchlorate anions. The same supramolecular motif could be independently prepared as [Fe(phen)(3)](2)center dot bphz(ClO4)(4)center dot xMeOH(2), and the [Ru(phenanthroline)(3)](2+) compound 3, isostructural to 1, was also prepared although a complete structure determination was prevented by low crystal quality. Compounds 1 and 3 are rare examples of how several large and different components can be assembled inside a 2D coordination network and provide a concept for multi-component self-assembly.

Department/s

Publishing year

2011

Language

English

Pages

5813-5817

Publication/Series

CrystEngComm

Volume

13

Issue

19

Document type

Journal article

Publisher

Royal Society of Chemistry

Topic

  • Natural Sciences
  • Physical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1466-8033