Orientational order in a glass of charged platelets with a concentration gradient
Author
Summary, in English
Colloidal dispersions of anisometric particles can display dynamical arrest and ordering involving both translational and rotational degrees of freedom. We show that orientational order can develop in glassy colloidal dispersions of charged platelets when a concentration gradient is imposed through solvent evaporation. Our model system of Laponite (LRD) platelets in deionized water has been extensively studied for its ergodic to non-ergodic transitions, and the existence of an underlying isotropic-nematic phase transition has been a subject of debate. We use small-angle X-ray scattering, dynamical light scattering and birefringence to show that the orientational order we observe does not result from an underlying, uniquely determined equilibrium state with orientational order, but from plastic deformation of the colloidal glass.
Department/s
Publishing year
2013
Language
English
Pages
9999-10004
Publication/Series
Soft Matter
Volume
9
Issue
42
Document type
Journal article
Publisher
Royal Society of Chemistry
Topic
- Natural Sciences
- Physical Sciences
Status
Published
ISBN/ISSN/Other
- ISSN: 1744-6848