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Synthesis of Formylsilanes through Oxidative Cleavage of α-Silyl Glycols.

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Author

Summary, in English

A convenient method for the synthesis and isolation of highly reactive formylsilanes by oxidative cleavage of α-silyl glycols is presented. The mild conditions provide an entry to acid- and heat-sensitive members of this theoretically intriguing class of compounds. The utility of the method is demonstrated through the isolation and subsequent diastereoselective derivatization of t-BuMe2- and t-BuPh2-formylsilanes, previously not reported in isolated form.

Publishing year

2013

Language

English

Pages

12268-12273

Publication/Series

Journal of Organic Chemistry

Volume

78

Issue

23

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Chemical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1520-6904