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A Diels-Alder Approach to a Communesin Model: A/B-Cyclization Route

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Author

Summary, in English

Compound 3, a model system for communesin F, was approached by using a Diels-Alder reaction for the introduction of the vicinal quaternary stereocentres. Subsequent introduction of A/B-ring system followed by D/E-ring closure gave hexacyclic system 22. All attempts to reduce this material to give compound 3 were, however, unproductive.

Publishing year

2015

Language

English

Pages

3441-3449

Publication/Series

European Journal of Organic Chemistry

Issue

16

Document type

Journal article

Publisher

John Wiley & Sons Inc.

Topic

  • Organic Chemistry

Keywords

  • Polycycles
  • Alkaloids
  • Natural products
  • Cyclization
  • Synthesis design

Status

Published

ISBN/ISSN/Other

  • ISSN: 1434-193X