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Reactivity of carbon dioxide toward zirconocene cations

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Author

Summary, in English

Cationic methyl- and phenylzirconocene species readily undergo insertion of CO2 into the zirconium-carbon bond, giving the corresponding dimeric carboxylato complexes 12 and 13 in quantitative yield. 12 was structurally characterized, displaying a bridging acetate ligand.

Publishing year

2005

Language

English

Pages

5772-5775

Publication/Series

Organometallics

Volume

24

Issue

23

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 1520-6041