Bis{μ-cis-1,3-bis-[(di-tert-butyl-phosphan-yl)-oxy]cyclo-hexane-κ(2) P:P'}bis-[carbonylnickel(0)] including an unknown solvent molecule.
Author
Summary, in English
The title compound, [Ni2(C22H46P2O2)2(CO)2], is located about a centre of inversion with the Ni(0) atom within a distorted trigonal-planar geometry. The cyclo-hexyl rings are in the usual chair conformation with the 1,3-cis substituents equatorially oriented. No specific inter-molecular inter-actions are noted in the crystal packing. A region of disordered electron density, most probably a disordered deuterobenzene solvent molecule, was treated using the SQUEEZE routine in PLATON [Spek (2009 ▶). Acta Cryst. D65, 148-155]. Its formula mass and unit-cell characteristics were not taken into account during refinement.
Department/s
Publishing year
2014
Language
English
Pages
176-177
Publication/Series
Acta Crystallographica Section E: Structure Reports Online
Volume
70
Issue
Pt 5
Document type
Journal article
Publisher
International Union of Crystallography
Topic
- Chemical Sciences
Status
Published
ISBN/ISSN/Other
- ISSN: 1600-5368