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Biomimetic Synthesis toward the Transtaganolides/Basiliolides.

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Author

Summary, in English

A concise biomimetic approach toward transtaganolides C and D involving an Ireland-Claisen rearrangement/intramolecular Diels-Alder reaction sequence suggesting the involvement of pericyclic reactions in the biosynthesis of these biologically active plant metabolites is presented. A final coupling reaction establishes the carbon framework of the transtaganolides.

Publishing year

2009

Language

English

Pages

657-660

Publication/Series

Organic Letters

Volume

11

Issue

3

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 1523-7052