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Analysis of Multiphase Transport Phenomena in PEMFCS by Incorporating Microscopic Model for Catalyst Layer Structures

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Author

Summary, in English

The catalyst layer (CL) in polymer electrolyte membrane (PEM) fuel cells is one of the key components regulating the overall performance of the cell. In PEM fuel cells, there are two CLs having identical composition for hydrogen oxidation (HO) and oxygen reduction (OR) reactions. There are four phases inside the CL, namely: carbon, Pt particles, ionomer and voids. In this work, a micro-model of the cathode CL has been developed mathematically using finite volume (FV) technique to investigate the transport phenomena of reactants and product species, ions and electrons by incorporating the above stated phases at the cathode side only, due to the fact that the OR reactions are the rate limiting as compared to HO reaction. The 3D CL has been reconstructed based on a regularly distributed sphere's method with dimensions 4.1 x 4.1 x 4.1 mu m(3). Platinum particles combined with carbon spheres (C/Pt) are regularly placed in the domain, an ionomer layer of a given thickness is extruded from the sphere surfaces. The C/Pt, ionomer and void distribution, as well as the triple phase boundary (TPB) are analysed and discussed. A microscopic model has been developed for water generation and species transport via Knudsen diffusion through the voids and the proton transport in the ionomer has been included here to aim for the rigorousness of the work. In addition, the electro-chemical reactions have been simulated on the surface of Pt particles fitlfilling the TBP conditions.

Department/s

Publishing year

2012

Language

English

Pages

903-912

Publication/Series

Proceedings Of The ASME International Mechanical Engineering Congress and Exposition, 2011, Vol 4, Pts A and B

Document type

Conference paper

Publisher

Amer. Soc. Mechanical Engineers

Topic

  • Energy Engineering

Keywords

  • PEMFC
  • catalyst layer
  • micro model
  • catalyst reconstruction

Conference name

ASME International Mechanical Engineering Congress and Exposition (IMECE), 2011

Conference date

2011-11-11 - 2011-11-17

Conference place

Denver, CO, United States

Status

Published