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On the Synthesis of Asymmetric and Dissymmetric Amino Analogues of Troger's Base

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Author

Summary, in English

Monoamino and diamino analogues of Troger's base have been synthesized by palladium-catalyzed aminations of the corresponding dihalo analogues using low catalyst loadings. Depending on the nature of the dihalo analogue (Br or 1). catalyst loading and the scale of the reaction, monoamino-monohalo and/or diamino analogues of Troger's base were obtained.

Publishing year

2009

Language

English

Pages

3120-3126

Publication/Series

Synthesis

Issue

18

Document type

Journal article

Publisher

Oxford Polytechnic, Oxford

Topic

  • Organic Chemistry

Keywords

  • halogen-lithium
  • Troger's base
  • palladium
  • aminations
  • catalysis
  • exchange

Status

Published

ISBN/ISSN/Other

  • ISSN: 0039-7881