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cis-Bis(acetato-kO)bis(dimethyl sulfide-kS)platinum(II)

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Summary, in English

The title compound, cis-[Pt(CH3COO)2(C2H6S)2], crystallizes in the P21/c space group with a pseudo-square-planar geometry. The complex forms centrosymmetric dimeric packing units, with C-H...O-Pt interactions and a short Pt...Pt distance [3.5868(2) Å]. The coordination mode of the acetate ligands is monodentate and they are oriented almost perpendicular to the coordination plane. Cambridge Structural Database [Allen (2002). Acta Cryst. B58, 380-388] data show a preferred staggered conformation with respect to the coordination plane for Me2S in complexes with Pt(II).

Publishing year

2008

Language

English

Pages

61-63

Publication/Series

Acta Crystallographica. Section C: Crystal Structure Communications

Volume

64

Document type

Journal article

Publisher

International Union of Crystallography

Topic

  • Organic Chemistry

Keywords

  • platinum compounds
  • data mining
  • crystallography

Status

Published

ISBN/ISSN/Other

  • ISSN: 0108-2701