Rydberg-Resolved Resonant Inelastic Soft X-Ray Scattering: Dynamics at Core Ionization Thresholds
Author
Summary, in English
Resonant inelastic x-ray scattering spectra excited in the immediate vicinity of the core-level ionization thresholds of N-2 have been recorded. Final states of well-resolved symmetry-selected Rydberg series converging to valence-level ionization thresholds with vibrational excitations are observed. The results are well described by a quasi-two-step model which assumes that the excited electron is unaffected by the radiative decay. This threshold dynamics simplifies the interpretation of resonant inelastic x-ray scattering spectra considerably and facilitates characterization of low-energy excited final states in molecular systems.
Department/s
Publishing year
2015
Language
English
Publication/Series
Physical Review Letters
Volume
114
Issue
13
Document type
Journal article
Publisher
American Physical Society
Topic
- Physical Sciences
Status
Published
ISBN/ISSN/Other
- ISSN: 1079-7114