Insertion of carbon dioxide into (PCP)Pd-II-Me bonds
Author
Summary, in English
A (PCP)PdMe complex has been synthesized and structurally characterized, displaying a very long Pd-Me bond. It is reactive toward CO2 insertion, giving the corresponding acetate in quantitative yield. The methyl complex can be regenerated using ZnMe2, and catalytic carboxylation is possible in benzene.
Publishing year
2005
Language
English
Pages
4500-4502
Publication/Series
Organometallics
Volume
24
Issue
19
Document type
Journal article
Publisher
The American Chemical Society (ACS)
Topic
- Organic Chemistry
Status
Published
ISBN/ISSN/Other
- ISSN: 1520-6041