Intermolecular vibrations of the water trimer, a matrix isolation study
Author
Summary, in English
Infrared spectra from 25 to 4000 cm(-1) have been recorded of water (H2O, D2O and (H2O)-O-18) matrix isolated in neon, argon, and krypton matrices. Intermolecular absorption bands of different isotopologues of the water trimer and tetramer have been assigned from concentration dependencies and diffusion behavior, using the well-known mid-infrared trimer and tetramer absorption bands as measures of the trimer and tetramer concentrations. The results are compared to ab initio calculations.
Department/s
Publishing year
2005
Language
English
Pages
7859-7864
Publication/Series
The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
Volume
109
Issue
35
Document type
Journal article
Publisher
The American Chemical Society (ACS)
Topic
- Theoretical Chemistry
- Atom and Molecular Physics and Optics
Status
Published
ISBN/ISSN/Other
- ISSN: 1520-5215