Systematic synthesis of functional unsymmetric FeZn model complexes for plant purple acid phosphatases
Author
Summary, in English
The heterodinuclear complexes [FeZn(L)(CH3CO2)(2)](+) (L = ICIMP or IPCPMP) are structural models for the dinuclear active sites of plant purple acid phosphatases They can be systematically synthesized from mononuclear iron complexes and enhance the rate of transesterification of 2-hydroxypropyl p-nitrophenyl phosphate, an assay for the catalytic hydrolysis performed by purple acid phosphatases (C) 2009 Elsevier B V All rights reserved
Publishing year
2010
Language
English
Pages
334-337
Publication/Series
Inorganic Chemistry Communications
Volume
13
Issue
3
Document type
Journal article
Publisher
Elsevier
Topic
- Atom and Molecular Physics and Optics
Keywords
- Transesterification
- Model complexes
- phosphatase
- Purple acid
- Dinuclear
- Bioinorganic chemistry
- Heterodinuclear
- Zinc
- Iron
- HPNP
Status
Published
ISBN/ISSN/Other
- ISSN: 1879-0259