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cis-{2,6-Bis[(di-tert-butyl-phosphan-yl)meth-yl]cyclo-hexyl-κ(3) P,C (1),P'}chloridopalladium(II).

Author

  • Daniel Olsson
  • Jacobus van Rensburg
  • Ola Wendt

Summary, in English

The Pd atom in the title compound, [Pd(CHP)Cl], has a distorted square-planar CClP coordination geometry with the ,,'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring.

Publishing year

2012

Language

English

Pages

1513-1513

Publication/Series

Acta Crystallographica Section E: Structure Reports Online

Volume

68

Issue

Pt 12

Document type

Journal article

Publisher

International Union of Crystallography

Topic

  • Chemical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1600-5368