cis-{2,6-Bis[(di-tert-butyl-phosphan-yl)meth-yl]cyclo-hexyl-κ(3) P,C (1),P'}chloridopalladium(II).
Author
Summary, in English
The Pd atom in the title compound, [Pd(CHP)Cl], has a distorted square-planar CClP coordination geometry with the ,,'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring.
Publishing year
2012
Language
English
Pages
1513-1513
Publication/Series
Acta Crystallographica Section E: Structure Reports Online
Volume
68
Issue
Pt 12
Document type
Journal article
Publisher
International Union of Crystallography
Topic
- Chemical Sciences
Status
Published
ISBN/ISSN/Other
- ISSN: 1600-5368