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Cleft molecules as organocatalysts in an asymmetric hetero-Diels-Alder reaction

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Author

Summary, in English

The synthesis and application of chiral carbocyclic cleft molecules derived from 2,3:6,7-dibenzobicyclo[3.3.1]nona-2,6-diene-4,8-diene in the hetero-Diels-Alder reaction of benzaldehydes and aminodiene 14 is presented. Catalysis by single hydrogen-bond activation gave up to 52% ee.

Publishing year

2007

Language

English

Pages

885-891

Publication/Series

Tetrahedron: Asymmetry

Volume

18

Issue

7

Document type

Journal article

Publisher

Elsevier

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 0957-4166