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Structure investigation of Ti-IV-BODOLates involved in the catalytic asymmetric reduction of ketones using catecholborane

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Author

Summary, in English

The complexes formed by the reaction of [Ti(OiPr)(4)] and bicyclo-octanediols (BODOLs) 1 and 2 (1:1) are useful as chiral catalysts in asymmetric reductions and were investigated by H-1 NMR spectroscopy and computational methods. A consistent picture emerged of head-to-tail dimers being kept together via a Ti-O-Ti-O mu-oxo bridge similar to the Ti-tartrates but different from the corresponding Ti-BINOLates and Ti-TADDOLates.

Publishing year

2004

Language

English

Pages

182-189

Publication/Series

Chemistry: A European Journal

Volume

10

Issue

1

Document type

Journal article

Publisher

Wiley-Blackwell

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 1521-3765