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A desymmetrization route to fused Troger's base analogues: Synthesis, isolation, and characterization of the first anti-anti diastereomer of a fused tris-Troger's base analogue

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Author

Summary, in English

A desymmetrization route to fused Troger's base analogues was developed. In this way, the synthesis of the first example of an anti-anti diastereomer of a fused tris-Troger's base analogue was accomplished. The resulting compound 5b is a nonlinear symmetric regioisomer obtained from p-bromoaniline in 7% yield. The corresponding syn-anti diastereomer 5a was obtained in 4% yield.

Publishing year

2005

Language

English

Pages

2019-2022

Publication/Series

Organic Letters

Volume

7

Issue

10

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 1523-7052