Crosslinked Polyamide Based on Main-Chain Type Polybenzoxazines Derived from a Primary Amine-Functionalized Benzoxazine Monomer
Author
Summary, in English
Two types of main-chain type polybenzoxazines with amide and benzoxazine groups as repeating units in the main chain, termed as poly(amide-benzoxazine), have been synthesized. They have been prepared by polycondensation reaction of primary amine-bifunctional benzoxazine with adipoyl and isophthaloyl dichloride using dimethylacetamide as solvent. Additionally, a model reaction is designed from the reaction of 3,3'-(4,4'-methylenebis(4,1-phenylene)) bis(3,4-dihydro-2H-benzo[e][1,3]oxazin-6-amine) with benzoyl chloride. The structures of model compound and polyamides are confirmed by Fourier transform infrared (FTIR) and proton nuclear magnetic resonance (H-1 NMR) spectroscopies. Differential scanning calorimetry and FTIR are also used to study crosslinking behavior of both the model compound and polymers. Thermal properties of the crosslinked polymers are also studied by thermogravimetric analysis. (C) 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 49: 4335-4342, 2011
Department/s
Publishing year
2011
Language
English
Pages
4335-4342
Publication/Series
Journal of Polymer Science. Part A, Polymer Chemistry
Volume
49
Issue
20
Document type
Journal article
Publisher
John Wiley & Sons Inc.
Topic
- Chemical Sciences
Keywords
- crosslinked polyamide
- main chain benzoxazine polymer
- polymerization
- behavior
- primary amine-functional benzoxazine
Status
Published
ISBN/ISSN/Other
- ISSN: 0887-624X