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Crystal structure of (piperidine-1-carbo-di-thio-ato-κ(2) S,S)[2-(pyridin-2-yl)phenyl-κ(2) C (1),N]palladium(II).

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Author

  • Mikhail Kondrashov
  • André Fleckhaus
  • Roman Gritcenko
  • Ola Wendt

Summary, in English

The title compound, [Pd(C11H8N)(C6H10NS2)], crystallizes with three similar and discrete mol-ecules in the asymmetric unit. The CNS2 donor set defines a distorted square-planar geometry around the Pd(II) atom, with very small deviations from planarity. The bidentate nature of the ligands gives fairly large deviations from the ideal 90° angles; the C-Pd-N angles are all around 81° and the S-Pd-S angles are around 75°. Mol-ecules pack via dispersion inter-actions.

Publishing year

2015

Language

English

Pages

166-166

Publication/Series

Acta crystallographica. Section E: Crystallographic communications

Volume

71

Issue

Pt 9

Document type

Journal article

Publisher

International Union of Crystallography

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 2056-9890