The browser you are using is not supported by this website. All versions of Internet Explorer are no longer supported, either by us or Microsoft (read more here: https://www.microsoft.com/en-us/microsoft-365/windows/end-of-ie-support).

Please use a modern browser to fully experience our website, such as the newest versions of Edge, Chrome, Firefox or Safari etc.

Multi-scale Measurement of (Amorphous) Polymer Deformation: Simultaneous X-ray Scattering, Digital Image Correlation and In-situ Loading

På svenska

Author

Summary, in English

This paper presents a method to investigate the behaviour of polymers on different scales during deformation using simultaneously collected synchrotron X-ray scattering, digital image correlation (DIC) and tensile loading. The method is demonstrated through experiments made on specimens of amorphous polycarbonate. Deformation is measured in-situ, simultaneously across different scales from the macroscopic deformation, measured using sensors on the tensile machine, to the full-field mesoscopic deformation, measured using DIC, down to the deformation of the nano-scale structure, studied using small and wide angle X-ray scattering (SAXS/WAXS). The DIC reveals highly inhomogeneous deformations that render conventional techniques for measuring deformation, such as extensiometers, virtually useless. The X-ray scattering is measured in several spatial points during continuous loading giving the evolution of the microstructure with respect to both spatial location and load level. The spatial mapping of the scattering reveals characters that would not be observed when only measuring at the centre point or measuring on a large area of the specimen, e.g. wide beam SAXS/WAXS or small angle neutron scattering (SANS). With these data, the macroscopic and the mesoscopic deformation can be correlated to the behaviour of the microstructure providing relevant information when developing micro-mechanical based constitutive models. The experimental results shown here indicate a direct correlation between the major principal strain direction and the maximum anisotropy direction of the SAXS patterns. The current approach can be extended to any kind of polymeric materials or polymer-based nano-composites.

Publishing year

2014

Language

English

Pages

1373-1383

Publication/Series

Experimental Mechanics

Volume

54

Issue

8

Document type

Journal article

Publisher

Springer

Topic

  • Mechanical Engineering

Keywords

  • Digital image correlation
  • Small angle X-ray scattering
  • Wide angle X-ray scattering
  • In-situ loading
  • Polycarbonate

Status

Published

ISBN/ISSN/Other

  • ISSN: 1741-2765