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Synthesis of a platinum(II) bis(trimethylsilyl)amido complex: A better starting material for the cyclometalation of pincer ligands

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Author

Summary, in English

Treatment of [(COD)PtCl2] with LiN(SiMe3)(2) gives [COD]PtClN(SiMe3)(2) in high yield. This product was fully characterized, including an X-ray structure. From a number of examples it is shown to be a very convenient starting material for the preparation of PXP platinum pincer complexes, giving excellent yields of the cyclometalated product under mild conditions.

Publishing year

2008

Language

English

Pages

4541-4543

Publication/Series

Organometallics

Volume

27

Issue

17

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 1520-6041