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Reactivity of palladium(II) methyl complexes towards CO2: formation of carbonate complexes

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Author

Summary, in English

Treatment of a benzene solution of (tmeda)PdMe2 or (dppe)PdMe2 with carbon dioxide gives the corresponding methyl bicarbonate complex, (L-L)PdMe(O2COH). These were characterised by NMR spectroscopy and elemental analysis. Under strictly dry conditions no reaction was observed. Recrystallisation of the tmeda bicarbonate complex from acetone yields the corresponding eta(2)-carbonate complex, which was characterised by X-ray crystallography. The reaction probably proceeds through attack by free carbonic acid on the dimethyl complex. (C) 2003 Elsevier B.V. All rights reserved.

Publishing year

2004

Language

English

Pages

1295-1298

Publication/Series

Inorganica Chimica Acta

Volume

357

Issue

4

Document type

Journal article

Publisher

Elsevier

Topic

  • Organic Chemistry

Keywords

  • Palladium complexes
  • Crystal structures
  • Carbon dioxide
  • Carbonate complexes

Status

Published

ISBN/ISSN/Other

  • ISSN: 0020-1693