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Hydride abstraction from eta(3)-allylic molybdenum complexes exploring various diaryl carbenium ion precursors. A study toward enantioselective hydride abstraction

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Author

Summary, in English

The efficiency of trityl bromide (4) and diaryl carbenium ion precursors 5-7 in hydride abstraction from a series of cyclohexenyl molybdenum complexes (2) was investigated. The novel nonracemic hydride abstractors 14a,b were designed and prepared and were shown to effectuate hydride abstraction from prochiral substrate 15 with modest enantioselectivity.

Publishing year

2002

Language

English

Pages

1583-1590

Publication/Series

Organometallics

Volume

21

Issue

8

Document type

Journal article

Publisher

The American Chemical Society (ACS)

Topic

  • Organic Chemistry

Status

Published

ISBN/ISSN/Other

  • ISSN: 1520-6041