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Ni-Cu ion exchange observed for Ni(II)-porphyrins on Cu(111)

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Author

  • Catherine M. Doyle
  • John P. Cunniffe
  • Sergey A. Krasnikov
  • Alexei Preobrajenski
  • Zheshen Li
  • Natalia N. Sergeeva
  • Mathias O. Senge
  • Attilio A. Cafolla

Summary, in English

A Ni-Cu ion exchange has been observed for (5,15-dibromo-10,20-diphenylporphyrinato)nickel(II) (NiDBrDPP) and (5,10,15,20-tetrakis-(4-bromophenyl) porphyrinato)nickel(II) (NiTBrPP) on Cu(111). The ion exchange proceeds at a faster rate for the NiDBrDPP/Cu(111) system compared to NiTBrPP/Cu(111). This is explained in terms of the macrocycle-substrate distance and the distortions

Department/s

Publishing year

2014

Language

English

Pages

3447-3449

Publication/Series

Chemical Communications

Volume

50

Issue

26

Document type

Journal article

Publisher

Royal Society of Chemistry

Topic

  • Chemical Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 1364-548X