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Diels-Alder adducts derived from the natural phthalide Z-ligustilide

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Author

Summary, in English

Z-Ligustilide, a naturally occurring phthalide isolated from Ligusticum porteri, underwent Diels-Alder reactions with different dienophiles yielding novel tricyclic products with potentially interesting biological properties. Where selectivity was possible, the reactions performed showed regio- and stereoselectivity. The experimental results with ethyl acrylate were compared with the selectivity predicted by ab initio calculations.

Publishing year

2007

Language

English

Pages

4215-4218

Publication/Series

Tetrahedron Letters

Volume

48

Issue

24

Document type

Journal article

Publisher

Elsevier

Topic

  • Organic Chemistry

Keywords

  • STAT3
  • Z-ligustilide
  • galiellalactone
  • ab initio
  • Diels-Alder

Status

Published

ISBN/ISSN/Other

  • ISSN: 0040-4039