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The coupling between translation and rotation for monomeric water in noble gas matrices.

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Author

Summary, in English

The rotation of water in noble gas matrices has been studied. It is shown that the rotation-translation coupling model of Friedmann and Kimel predicts rotation line spacings, which are close to the experimental observations for H2O, D2O, and HDO, when gas phase rotation constants are used. The model gives intensity estimates in reasonable agreement with the observations for the local oscillator bands, which accompany the rotation spectrum. It also predicts the intensity variations in the bending region of H2O between neon, argon, and krypton matrices.

Publishing year

2013

Language

English

Publication/Series

Journal of Chemical Physics

Volume

138

Issue

24

Document type

Journal article

Publisher

American Institute of Physics (AIP)

Topic

  • Physical Sciences
  • Atom and Molecular Physics and Optics
  • Natural Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 0021-9606