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Azinyl sulfides. LXXXI. 14-Phenyl-7-thiapyrano[2,3-c;6,5-c ']diquinoline-14-carbonitrile

Author

  • Céline Besnard
  • C Kloc
  • Theo Siegrist
  • Christer Svensson
  • K Pluta

Summary, in English

The molecules of the title compound, C26H15N3S, have a pentacyclic ring system which is almost planar, with the central ring in a flattened boat conformation. The folding angle between the two quinoline rings is 6.75 ( 7)degrees. The 14- phenyl substituent is in a quasi- axial conformation, while the 14-cyano substituent is in a quasi- equatorial conformation with respect to the thiopyran ring. The S center dot center dot center dot C - C-phenyl and S center dot center dot center dot C - C-CN angles are 116.8 ( 2) and 129.3 ( 2) degrees, respectively. The plane of the phenyl group is nearly coplanar with the plane bisecting the dihedral angle of the pentacyclic ring system.

Publishing year

2005

Language

English

Pages

377-379

Publication/Series

Acta Crystallographica. Section C: Crystal Structure Communications

Volume

61

Issue

Pt 6

Document type

Journal article

Publisher

International Union of Crystallography

Topic

  • Chemical Sciences
  • Physical Sciences
  • Natural Sciences

Status

Published

ISBN/ISSN/Other

  • ISSN: 0108-2701